Abstract
2-Methyl-2-oxazoline (MeOZO) was polymerized by using 1-chloro-1, 3-butadiene—butadiene copolymer as an initiator having reactive allylic chlorine. Polymerization was carried out in benzonitrile or in bulk. The active species of the MeOZO graft copolymerization was covalent-bonded alkyl chloride. The resulted graft copolymer was hydrolyzed under alkaline conditions to poly(butadiene-g-ethyleneimine). The structure of the graft copolymer was characterized by IR, NMR, as well as by an elemental analysis.
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Saegusa, T., Yamada, A. & Kobayashi, S. Preparation of Poly(butadiene-g-N-acetylethyleneimine) and Its Hydrolysis to Poly(butadiene-g-ethyleneimine). Polym J 11, 53–58 (1979). https://doi.org/10.1295/polymj.11.53
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DOI: https://doi.org/10.1295/polymj.11.53
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