Abstract
Optically active polymers of trans- and cis-2-methyl-1,3-pentadienes were prepared by asymmetric inclusion polymerization in deoxycholic acid canals. All of the polymers prepared were found to be of 1,4-trans, head-to-tail structures and showed high optical rotations of (+) sign. It was also found that the optical activity changes reversibly with temperature.
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Miyata, M., Kitahara, Y. & Takemoto, K. Functional Monomers and Polymers. LXXXIII. Synthesis of Optically Active Polymers from trans- and cis-2-Methyl-1,3-pentadienes by Asymmetric Inclusion Polymerization in Deoxycholic Acid Canals. Polym J 13, 111–113 (1981). https://doi.org/10.1295/polymj.13.111
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DOI: https://doi.org/10.1295/polymj.13.111
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