Abstract
Alternating copolymers of methyl α-fluoroacrylate (MFA) with styrene (S), α-deuteriostyrene and β,β-dideuteriostyrene were prepared at −15°C using ethyl aluminium sesquichloride as a complexing agent. The 300 MHz 1H, 20 MHz 13C, 75 MHz 13C, and 282 MHz 19F NMR spectra of the copolymers were recorded and analyzed to obtain information about their stereochemical structures. The coisotacticity parameter of poly(MFA-alt-S) was determined to be 0.66.
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Majumdar, R., Lin, Ft. & Haruwood, H. Synthesis and NMR Characterization of the Alternating Copolymer of Methyl α-Fluoroacrylate with Styrene. Polym J 16, 175–186 (1984). https://doi.org/10.1295/polymj.16.175
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DOI: https://doi.org/10.1295/polymj.16.175
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