Abstract
Polybutadiene was separated by isomeric structure using high performance liquid chromatography. With reversed-phase mode using a cross-linked styrene gel as a stationary phase and a mixture of acetonitrile and dichloromethane as an eluent, the polymer was separated by phase separation mechanism. With a cross-linked acrylamide gel and a mixture of hexane and dichloromethane (normal phase), the samples were eluted in order of 1,2 (vinyl), cis-1,4, and trans-1,4 structure by adsorption mechanism. The resolution by adsorption mechanism was better than one by phase separation mechanism. If acrylonitrile gel was used as stationary phase in the normal phase, samples were adsorbed only weakly to the gel and the resolution was not good.
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S. Teramachi, A. Hasegawa, Y. Shima, M. Akatsuka, and M. Nakajima, Macromolecules, 12, 992 (1979).
M. Danielewicz and M. Kubin, J. Appl. Polym. Sci., 26, 951 (1981).
M. Danielewicz, M. Kubin, and S. Vozka, J. Appl. Polym. Sci., 27, 3629 (1981).
G. Glöckner, H. Kroschwitz, and Ch. Meissner, Acta Polymerica, 33, 614 (1982).
G. Glöckner and R. Koningsveld, Makromol. Chem., Rapid Commun., 4, 529 (1983).
G. Glöckner, J. H. M. van den Berg, N. L. J. Meijerink, and T. G. Scholte, R. Koningsveld, Macromolecules, 17, 962 (1984).
G. Glöckner and J. H. M. van den Berg, Chromatographia, 19, 55 (1984).
G. Glöckner, J. H. M. van den Berg, N. L. J. Meijerink, T. G. Scholte, and R. Koningsveld, J. Chromatogr., 317, 615 (1984).
G. Glöckner and J. H. M. van den Berg, J. Chromatogr., 352, 511 (1986).
S. Mori, Y. Uno, and M. Suzuki, Anal. Chem., 58, 303 (1986).
G. Glöckner and J. H. M. van den Berg, J. Chromatogr., 384, 135 (1987).
G. Glöckner, J. Chromatogr., 403, 280 (1987).
G. Glöckner and J. H. M. van den Berg, Chromatographia, 24, 233 (1987).
S. Mori and Y. Uno, J. Appl. Polym. Sci., 34, 2689 (1987).
S. Mori and Y. Uno, Anal. Chem., 59, 90 (1987).
G. Glöckner, M. Stickler, and W. Wunderlich, Fresenius Z. Anal. Chem., 328, 76 (1987).
G. Glöckner, M. Stickler, and W. Wunderlich, Fresenius Z. Anal. Chem., 330, 46 (1988).
S. Teramachi, A. Hasegawa, Y. Shigekuni, and S. Matunaga, Polym. J., 21, 803 (1989).
G. Glöckner, J. Appl. Polym. Sci., Appl. Polym. Symp., 43, 39 (1989).
S. Mori, J. Appl. Polym. Sci., Appl. Polym. Symp., 43, 65 (1989).
G. Glöckner and A. H. E. Müller, J. Appl. Polym. Sci., 38, 1761 (1989).
H. Sato, H. Takeuchi, and Y. Tanaka, Makromol. Chem., Rapid Commun., 5, 719 (1984).
H. Sato, H. Takeuchi, and Y. Tanaka, Macromolecules, 19, 2613 (1986).
H. Sato, K. Mitsutani, I. Shimizu, and Y. Tanaka, J. Chromatogr., 447, 387 (1988).
N. Asada, H. Hosozawa, A. Toyoda, and H. Sato, Rubber Chem. Technol., 63, 181 (1990).
H. Sato, M. Sasaki, and K. Ogino, Polym. J., 21, 965 (1989).
H. Sato, K. Ogino, S. Maruo, and M. Sasaki, J. Polym. Sci., Polym. Phys. Ed., to be published.
K. Ogino and H. Sato, Kobunshi Ronbunshu, 46, 667 (1989).
H. Sato, K. Takebayashi, and Y. Tanaka, Macromoleclues, 20, 2418 (1987).
R. A. Orwoll, “Polymer Handbook,” 3rd ed., Wiley Interescince, New York, N. Y., 1989, p VII/517.
H. Inagaki, T. Miyamoto, and F. Kamiyama, Makromol. Chem., 175, 187 (1974).
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Sato, H., Sasaki, M. & Ogino, K. Separation of Polybutadiene Depending on Isomeric Stuructures by High Performance Liquid Chromatography. Polym J 23, 23–27 (1991). https://doi.org/10.1295/polymj.23.23
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DOI: https://doi.org/10.1295/polymj.23.23