Abstract
The crystalline junction size ζ, which is the number of consecutive ethylene units per crystalline sequence such as –[–CH2–CH2–]–, in an ethylene–propylene (EP) copolymer gel was determined from gel-melting temperatures using the Takahashi theory. In order to examine the correlation between the size ζ and number-average length of ethylene sequences estimated from NMR measurements, an ethylene sequence distribution curve of the copolymer was established from 13C NMR data assuming 1st-order Markov statistics and number-average length in number of ethylene units (L[EE···E]) was calculated from its distribution curve. The average length L[EE···E] determined from this curve was in good agreement with that calculated directly from E/P triad data of NMR. Moreover, number-average length (L[EE···E≥5]) of ethylene sequences greater than or equal to 5, whose value is the crystallizable minimum number of consecutive ethylene units in an EP copolymer, approximately agreed with the junction size ζ in gel, i.e., ζ≃L[EE···E≥5].
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Moteki, Y., Okabe, M., Takahashi, M. et al. Study of Polyolefin Gel in Organic Solvents IX. Ethylene Sequence Distribution of Ethylene–Propylene Random Copolymer and Crystalline Junction Size in Its Thermoreversible Gel. Polym J 26, 1002–1012 (1994). https://doi.org/10.1295/polymj.26.1002
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DOI: https://doi.org/10.1295/polymj.26.1002