Abstract
Tacticity simulations of poly(vinyl acetate-co-vinyl propionate) [poly(VAc-co-VPr)], poly(vinyl acetate-co-vinyl decanoate) [poly(VAc-co-VD)] and poly(vinyl acetate-co-vinyl pivalate) [poly(VAc-co-VP)] were tried by a terminal model. Cotacticities for vinyl acetate (VAc)/vinyl pivalate (VPr) and vinyl acetate (VAc)/vinyl decanoate (VD) were well simulated and coisotactic parameters for these systems could be estimated. But the tacticities of poly(VAc-co-VP) could not be well simulated by the terminal model indicating penulutimate effect and simulation by penultimate model was tried.
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Yamamoto, T., Hanatani, M., Matsumoto, T. et al. Tacticities of Copoly(vinyl ester)s Obtained by Radical Polymerization. Polym J 26, 417–421 (1994). https://doi.org/10.1295/polymj.26.417
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DOI: https://doi.org/10.1295/polymj.26.417