Abstract
Polymerization of p- and m-menthoxycarbonylphenyl isocyanides having various optical purities has been performed by use of a Pd-Pt μ-ethynediyl dinuclear complex as an initiator and the induction of the screw-sense of the resulting helical polymers has been examined. The absolute value of optical rotations and the Cotton effect at about 365 nm in CD spectrum nonproportionally increase with increase in the optical purity of menthoxycarbonylphenyl isocyanides. In the polymers of p-menthyloxycarbonylphenyl isocyanide a positive nonlinear effect is observed while m-substituted analogs show a negative one.
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Takei, F., Onitsuka, K. & Takahashi, S. Nonproportional Effects of Optical Purity of Chiral Aryl Isocyanide Monomers Possessing (d) or (l)- Menthoxycarbonyl Groups on Induction of Screw-Sense in Poly(aryl isocyanide)s. Polym J 31, 1029–1032 (1999). https://doi.org/10.1295/polymj.31.1029
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DOI: https://doi.org/10.1295/polymj.31.1029