Abstract
Unlike ordinary linear polymers, dendritic architecture is unique in the terms of its elaborative capability for total control over molecular design parameters at the single molecular level, i.e., molecular size, branching pattern, structure, and morphology, thereby provides a new platform for the creation of functional materials with nanometer–scale precision. This review mainly concerns recent works on the development of dendritic nanomaterials with a focus on photo– and spin–related functionalities. Strategy for the incorporation of chromophores to build up light–harvesting antennae is presented with an emphasis on morphology and size effects. Dendritic macromolecules for photoinduced electron transfer are categorized based on chromophores that serve as the active center to absorb light and trigger photochemical process. In this context, dendrimers bearing porphyrin, conjugated polymer, and fullerene for realization of long–lived charge–separation state and light energy conversion are highlighted. On the other hand, design of dendritic macromolecules for spin–functional materials is focused on dendronized organic radicals and dendritic coordination polymers. Especially, spin–functional soft materials with an aim for spin manipulation and novel magnetic–optical switches are emphasized.
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He, Z., Ishizuka, T. & Jiang, D. Dendritic Architectures for Design of Photo– and Spin–Functional Nanomaterials. Polym J 39, 889–922 (2007). https://doi.org/10.1295/polymj.PJ2007006
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DOI: https://doi.org/10.1295/polymj.PJ2007006
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