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Direct introduction of hydroxyl groups in polystyrene chain ends prepared by atom-transfer radical polymerization

Polymer Journal volume 52, pages 57–64 (2020)Cite this article

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Abstract

We report a method to directly introduce a hydroxyl group at the omega chain end of polystyrene prepared by atom-transfer radical polymerization. To achieve the quantitative conversion of the bromine group to a hydroxyl group, the transfer reaction of a carbocation with water was exploited. This transfer reaction is a well-known reaction in cationic polymerization. The quantitative conversion and chemical structures of the hydroxyl-terminated PS were characterized using 1H nuclear magnetic resonance spectroscopy, matrix-assisted laser desorption/ionization time-of-flight mass spectrometry and high-performance liquid chromatography. In addition, alcohol-based compounds were used to introduce acetonide and propane groups into PS-Br.

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Acknowledgements

This work was supported by the Basic Science Research Program through the National Research Foundation of Korea (NRF) grant funded by the Korean government (MSIP) (NRF-2018R1A2B6005119).

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Authors and Affiliations

  1. Department of Polymer Science and Engineering, Pusan National University, Busan, 46241, Korea

    Kyoungho Kim, Min Guk Seo & Hyun-jong Paik

  2. Department of Chemistry, Kwangwoon University, Seoul, 01897, Korea

    Jinyoung Jung & Heung Bae Jeon

  3. Department of Chemistry and Division of Advanced Materials, Pohang University of Science and Technology (POSTECH), Pohang, 37673, Korea

    Junyoung Ahn & Taihyun Chang

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  1. Kyoungho Kim
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Correspondence to Heung Bae Jeon or Hyun-jong Paik.

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Kim, K., Seo, M.G., Jung, J. et al. Direct introduction of hydroxyl groups in polystyrene chain ends prepared by atom-transfer radical polymerization. Polym J 52, 57–64 (2020). https://doi.org/10.1038/s41428-019-0250-z

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