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| Open AccessAn electric molecular motor
An electrically driven motor on the molecular scale based on [3]catenane is described, in which two cyclobis(paraquat-p-phenylene) rings operate by means of redox reactions, demonstrating highly unidirectional movement around a circular loop.
- Long Zhang
- , Yunyan Qiu
- & J. Fraser Stoddart
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A tape-reading molecular ratchet
A molecular ratchet, in which a crown ether is pumped from solution onto an encoded molecular strand by a pulse of chemical fuel, opens the way for the reading of information along molecular tapes.
- Yansong Ren
- , Romain Jamagne
- & David A. Leigh
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Article |
An elastic metal–organic crystal with a densely catenated backbone
A rubber-like, metal–organic crystal is reported with a mechanically interlocked catenane backbone, which could allow for easy guest molecule uptake and release.
- Wenjing Meng
- , Shun Kondo
- & Hiroshi Sato
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A catalysis-driven artificial molecular pump
A molecular-scale pump whose operation is driven by a catalytic process when in the presence of chemical fuel is autonomous, within an operating window, as long as the fuel lasts.
- Shuntaro Amano
- , Stephen D. P. Fielden
- & David A. Leigh
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Article |
Self-assembly of a layered two-dimensional molecularly woven fabric
An anion and metal ion template is used to form woven polymer patches that are joined together by polymerization into a fully woven, two-dimensional, molecular patchwork.
- David P. August
- , Robert A. W. Dryfe
- & Robert J. Young
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Article |
Tying different knots in a molecular strand
A molecular strand can be knotted and unknotted into three different topologies, depending on the complexing metal ion used (copper or lanthanide or none).
- David A. Leigh
- , Fredrik Schaufelberger
- & Julien Segard
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Article |
Self-assembled poly-catenanes from supramolecular toroidal building blocks
Nanoscale toroids with a high percentage of poly-catenation and radii of up to about 13 nm are kinetically organized using fibrous supramolecular assemblies with intrinsic curvature and a solvent-mixing strategy.
- Sougata Datta
- , Yasuki Kato
- & Shiki Yagai
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Letter |
An autonomous chemically fuelled small-molecule motor
A system is described in which a small macrocycle is continuously transported directionally around a cyclic molecular track when powered by irreversible reactions of a chemical fuel; such autonomous chemically fuelled molecular motors should find application as engines in molecular nanotechnology.
- Miriam R. Wilson
- , Jordi Solà
- & David A. Leigh