Abstract
An ion embedded in warm/hot dense plasmas will greatly alter its microscopic structure and dynamics, as well as the macroscopic radiation transport properties of the plasmas, due to complicated many-body interactions with surrounding particles. Accurate theoretically modeling of such kind of quantum many-body interactions is essential but very challenging. In this work, we propose an atomic-state-dependent screening model for treating the plasmas with a wide range of temperatures and densities, in which the contributions of three-body recombination processes are included. We show that the electron distributions around an ion are strongly correlated with the ionic state studied due to the contributions of three-body recombination processes. The feasibility and validation of the proposed model are demonstrated by reproducing the experimental result of the line-shift of hot-dense plasmas as well as the classical molecular dynamic simulations of moderately coupled ultra-cold neutral plasmas. Our work opens a promising way to treat the screening effect of hot and warm dense plasma, which is a bottleneck of those extensive studies in high-energy-density physics, such as atomic processes in plasma, plasma spectra and radiation transport properties, among others.
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Introduction
Warm/hot dense plasma exists widely in all types of stars1, the interior of giant planets2 and inertial confinement fusions3,4. Studies to these high-energy-density plasmas have been attracting wide attentions and extensive experiments have been made to explore their microscopic and macroscopic properties on large-scale scientific facilities of linac coherent light source (LCLS) X-ray laser5,6,7, national ignition facility (NIF)8 and Sandia Z facility9,10,11, etc. For atoms embedded in dense plasma, strong plasma screening effects are encountered due to complicated many-body interactions with the surrounding plasma, which significantly affects the atomic energy levels and wave functions, resulting in ionization potential depression (IPD), line shift, and remarkable changes in the photon, electron, and ion scattering cross sections12,13. In addition, the screening effects would further change the plasma properties simulation due to the basic atomic data applied in modeling plasma, such as the equation of state (EOS) and plasma spectra14,15, etc. Therefore, understanding the screening effects is essential for both fundamental researches and applications.
On the side of theory, various models have been developed to describe the plasma screening effects since the pioneering work of Debye and Hückel16, the well-known Debye–Hückel model was proposed in 1920s for non-degenerate and weakly coupled plasmas. Thomas–Fermi (TF) screening and self-consistent field ion-sphere (IS) models have been developed to treat the electron screening effects for degenerate plasmas17,18. Numbers of analytic models, such as the uniform electron gas model (UEGM)19, Ecker–Kröll (EK)20, Stewart–Pyatt (SP)21, and the models based on the analytic fits to IS potentials22,23,24, are proposed and widely used in the calculation of IPDs and line shifts in dense plasmas. Note that these models are developed based on the electron distribution from Boltzmann or Fermi–Dirac statistics, and their applications in treating hot dense plasmas are very limited due to the complicated many-body correlations involved in modeling dense plasma. The predictions from the above models have discrepancies to the spectra, line shifts, and IPDs in the latest high-precision spectra experiments of warm/hot dense plasmas5,6,7,25,26,27,28. Then, attempts for a better interpretation of the new measured IPD data have been made using different numerical and simulation methods, including Two-step Hartree–Fock (HF) calculations29, quantum statistical approach30,31, simulations based on the finite-temperature density functional theory32, and classical molecular dynamics simulations33.
On the side of the experiment, with the recent advances in obtaining a uniform, well-characterized, and high-energy-density plasmas, it becomes possible to precisely measure the ionic energy level shift in warm/hot dense plasmas5,25,26,27. The line-shift experiments are of high relevance to benchmarking electron screening models, since the line shift reflects the difference between the level shifts of two relevant energy states, which is very sensitive to the electron screening effects. Lately, Stillman et al.27 and Beiersdorfer et al.28 reported high-precision line-shift measurements of Al11+ and Cl15+ in hot-dense plasmas produced by high-intensity short-pulse lasers. They have used Li and Rosmej’s analytical model23 to calculate the line shifts but the results obviously deviate from the experimental ones. In order to resolve the discrepancies between measurements and calculations, quite a few simulations have been performed by using other models, including the numerical self-consistent field IS models34,35,36, the line-shift model based on SP screening potential37 and other analytical fits of IS models34,38,39. Unfortunately, these models only work for Cl15+ (1s3p−1s2) but fail for Al11+ (1s2p−1s2). In a word, the study of screening effects of warm/hot dense plasma presents still a largely unresolved problem, which is essentially determined by the many-body interactions between the specific ion and the plasma environment.
In this paper, a statistical electron screening model is proposed to describe the complicated many-body interactions of warm/hot dense plasmas. In this model, the collisions between plasma electrons and target ion, in particular, the most important three-body recombination processes strongly dependent on the state of the target ion, are taken into account in determining the electron distribution. Note that the target ion is used to represent the studied ion embedded in plasmas hereafter in the paper. This atomic-state-dependent screening model is validated by the line shifts of Al11+ (1s2p−1s2) and Cl15+ (1s3p−1s2) transitions in the latest experiments of Stillman et al.27 and Beiersdorfer et al.28, as well as the classical molecular dynamic simulations on the electron distribution of moderately coupled ultra-cold neutral plasmas (UNPs).
Results and discussion
Model formulation
In this work, the main goal is to treat the atomic structure of the atom/ion embedded in hot plasma. The present model is based on wave-function-based approach, in which the plasma field is usually represented as a screening model and the structure of target ion can be computed by solving Schrödinger or Dirac equation. The plasma-electron density distribution around the target ion in plasmas is the kernel of an electron screening model. This distribution is determined by all collision processes between electrons and the target ion.
The plasma-electron density of previous wave-function-based screening models, including Debye–Hückel, self-consistent field IS, UEGM, EK, and SP, is usually based on Fermi–Dirac distribution or Boltzmann distribution. For the electrons with Fermi–Dirac distribution
the number density of electrons is given by \(\rho _{{\mathrm{FD}}}\left( {\boldsymbol{r}} \right) = \frac{1}{{2\pi ^2\hbar ^3}}\int _0^\infty f_{{\mathrm{FD}}}\left( {p,{\boldsymbol{r}}} \right)p^2{\mathrm{d}}p\), where μ is the chemical potential, \({{\Phi }}\left( {\boldsymbol{r}} \right)\) is the total effective potential at position r, and p is the magnitude of electron momentum. In some popular wave-function-based screening models, such as the self-consistent field IS and SP, only contributions of free electrons are considered and \(p > p_0\left( {\vec r} \right) = \sqrt {2m_{\mathrm{e}}e{{\Phi }}\left( {\vec r} \right)} \) is applied to the Fermi–Dirac distribution to guarantee the electron energy to be positive18,19,20,21,22,23,24. However, in moderately/strongly coupled or dense plasmas with high-density free electrons, three-body recombination processes will happen significantly when the free electrons approach the target ion, and then affect the electron distribution of the target ion, as shown in Fig. 1. For the convenience of numerical calculation, the recombined bound electrons are usually treated as negative-energy ones with momentum \(p \,< \, p_0\left( {\vec r} \right)\).
The present model is proposed to extend these previous screening models by considering the contribution of negative-energy electron due to the inelastic collisions between target ion and plasma electrons. For weakly coupled plasmas, the mean kinetic energy of an electron is much larger than its mean potential energy and the free-electron distribution dominates the total electron density distribution. But for moderately/strongly coupled or dense plasmas, the distribution of negative-energy electron around the target ion is expected to deviate from equilibrium and play an important role in the total electron density distribution. In this case, the IPDs and line shifts of target ions will be impacted largely by the electron screening effects and cannot be accurately determined by the electron distribution of an equilibrium plasma consisting of free electrons, ions, and atoms. When taking into account the electron-screening effect on the \(nln\prime l\prime \) state of the target ion, the contribution of the \(nln\prime l\prime \) state and the transitions involved the \(nln\prime l\prime \) state should be excluded from the electron density distribution. In the case of Al11+ \(\left( {1s2p} \right)\), the contribution of the electrons recombined into \(1s2p(nl \cdots )\) states are considered in the present model, including
Therefore, the obtained negative-energy electron populations differ from the ones of the equilibrium model, which is the statistical average over all possible electron state populations.
Meanwhile, the laboratory plasmas are produced with intense ultrashort laser pulses and are non-equilibrium plasmas27,28. Therefore, in the present model, the negative-energy electron distribution is obtained through solving the rate equation. For simplicity, the plasma free electrons are assumed to be in equilibrium and the steady-state approximation is applied to obtain the distribution of negative-energy state for the given free-electron temperature and density. We consider a steady-state plasma with the number density \(n_{\mathrm{e}}\) of free electrons and the number density \(n_{{\mathrm{ion}}}\) of singly charged ions. The atom with a specifically bound state j can be formed through the three-body recombination of the target ion and its number density \(n_{{\mathrm{atom}}}^j\) can be determined by
Here, \(\alpha _j\) and \(\beta _j\) are the rate coefficients of electron collision ionization and three-body recombination, \(K_{j^\prime j}\) and \(K_{jj^\prime }\) are the rate coefficients of excitation and de-excitation, respectively.
In order to describe the non-equilibrium feature of plasma-electron distribution around the target ion, we defined a non-equilibrium coefficient \(\chi ^j\) and \(n_{{\mathrm{atom}}}^j = \chi ^jn_{{\mathrm{atom}},{\mathrm{equil}}}^j\). Here \(n_{{\mathrm{atom}},{\mathrm{equil}}}^j\) is the population density for an equilibrium system with the same number densities of \(n_{\mathrm{e}}\) and \(n_{{\mathrm{ion}}}\) can be calculated by using Fermi–Dirac statistics. Combining the classical scattering and equilibrium distribution, the non-equilibrium coefficient is given by
where \({\mathrm{Erf}}\left( x \right)\) is the error function and \(\varepsilon _r = e{{\Phi }}\left( {\boldsymbol{r}} \right) - p^2/2m_{\mathrm{e}}\) is the absolute energy of the negative-energy electron. The details of the deviation of Eq. (4) are presented in Supplementary Note 1.
With the non-equilibrium coefficient \(\chi \left( {{\boldsymbol{p}},{\boldsymbol{r}}} \right)\) obtained, the negative-energy density distribution can be calculated with \(f_{{\mathrm{FD}}}\left( {{\boldsymbol{p}},{\boldsymbol{r}}} \right)\chi \left( {{\boldsymbol{p}},{\boldsymbol{r}}} \right)\), and the total plasma-electron density is given by
Due to the degeneracy effect (i.e., the Pauli exclusive principle) between the recombined and initially bound electrons, the recombined electron prefers to populate the outer orbital unoccupied. Therefore, the integration limit of the first term of Eq. (5) should be changed and the plasma-electron density around the target ions within a specific bound state can be obtained
In Eq. (6), the momentum p of the negative-energy electron is larger than \(\sqrt {2m_{\mathrm{e}}(\varepsilon _{\mathrm{b}} - e{{\Phi }}\left( {\boldsymbol{r}} \right))} \), where \(\varepsilon _{\mathrm{b}}\) is the energy of the outermost bound electron and its value will significantly affect the negative-energy electron distribution of the target ion.
The total effective potential \({{\Phi }}({\boldsymbol{r}})\) of the target ion can be obtained from
where \(\delta \rho \left( {\boldsymbol{r}} \right) = \rho \left( {\boldsymbol{r}} \right) - \rho _{\mathrm{e}}\) is the plasma-electron density fluctuation induced by the presence of the target ion, \(\rho _{\mathrm{e}}\) is the mean free-electron density, \(\rho _{\mathrm{b}}\left( {\boldsymbol{r}} \right)\) is the density of initially bound electrons, and can be calculated by using multi-configuration Dirac–Fock approach40,41. It can be found that \({{\Phi }}({\boldsymbol{r}})\) and \(\delta \rho \left( {\boldsymbol{r}} \right)\) in Eq. (7) are dependent on each other and can be calculated with an iteration approach (see the “Methods” section).
In Fig. 2, we show the electron densities \(\rho \left( {\boldsymbol{r}} \right)/\rho _{\mathrm{e}}\) obtained from the present model together with those from Debye–Hückel model and IS model at the position r with \({{\Phi }}\left( {\boldsymbol{r}} \right) = 1/(4\pi \varepsilon _0a_{{\mathrm{WS}}})\), where \(a_{{\mathrm{WS}}}\) is the Wigner–Seitz radius. As well known, the Debye–Hückel and ion sphere screening models are only valid under the weak-coupling and strongly degeneracy limit conditions, respectively. As shown in Fig. 2, the present model converges to Debye–Hückel model and IS model (corresponding to the free-electron distribution) at the corresponding plasma conditions. This indicates that the present model is more accurate and provides a unified framework for the electron screening of plasmas with wide range of temperatures and densities.
Line-shift calculation
For demonstration, we apply the model to the computation of the line shifts (see the “Methods” section) in the latest experiments27,28. In the experiments, the laser-produced hot-dense and weakly coupled non-equilibrium plasmas with (ρe, Te) = (1–5 × 1023 cm−3, 250–375 eV) for Al11+ 27 and (ρe, Te) = (3–6 × 1 023 cm−3, 600–650 eV) for Cl15+28, respectively. The Coulomb coupling parameters \(\Gamma _{\mathrm{e}} = e^2/(4\pi \varepsilon _0a_{{\mathrm{WS}}}k_{\mathrm{B}}T_{\mathrm{e}})\) are about 0.03–0.07, the charge state number Q of Al11+and Cl15+ are 11 and 15, respectively. We first compute, using the present model, the electron distribution fluctuations \(\delta \rho ({\boldsymbol{r}})\) of Al11+ and Cl15+ as well as a single-charged target ion with Q = 1 for comparison, for \(\rho _{\mathrm{e}} = 3 \times 10^{23}{\mathrm{cm}}^{ - 3},\,T_{\mathrm{e}} = 300\,{\mathrm{eV}}\,{\mathrm{and}}\,\Gamma _{\mathrm{e}} = 0.052\). The results are shown in Fig. 3a together with those from other models. It is shown that for the case of Q = 1, the present results are consistent with the results of Fermi–Dirac distribution. However, for the cases of Al11+(Q = 11), present results are very different from those of Fermi–Dirac distribution as shown in Fig. 3b. This indicates that \({{\Gamma }}_{\mathrm{e}}\) is independent of the Q, whereas the electron distribution around the target ion is sensitive to the ratio of the potential and kinetic energy of the electron, which can be approximated by \(e{{\Phi }}\left( r \right)/k_{\mathrm{B}}T \approx Qe^2/(4\pi \varepsilon _0{\boldsymbol{r}}k_{\mathrm{B}}T)\). In the present case of Q = 1,\(e{{\Phi }}\left( r \right) \,< \,k_{\mathrm{B}}T\) and the electron distribution of the present model is very close to the Fermi–Dirac one. While in the present case of Q = 11 and 15, \(e{{\Phi }}\left( r \right) \,> \,k_{\mathrm{B}}T\) and the negative-energy electron distribution is quite different from the Fermi–Dirac one due to the contribution of three-body recombination processes, see Supplementary Discussion for details. Thus, for moderately/strongly coupled or dense plasmas with \(e{{\Phi }}\left( r \right) \,> \, k_{\mathrm{B}}T\), the contribution of three-body recombination processes becomes important and should be included in the calculation.
By using the plasma-electron density fluctuation \(\delta \rho (r)\), the line shifts of Al11+ (1s2p−1s2) and Cl15+ (1s3p−1s2) are computed (see the “Methods” section). The results are shown in Fig. 4 together with the experimental results27,28 and the results from the numerical calculations of multi-configuration-Dirac–Fock self-consistent finite-temperature IS model (MCDF-SCFTIS)34 and the average-atom IS model (AA-IS)35,36. It is shown that the present results are in very good agreement with the experimental results for both Al11+and Cl15+. The results of MCDF-SCFTIS and AA-IS models are in good agreement with the experimental results for Cl15+ (1s3p−1s2) but are obviously underestimated for Al11+ (1s2p−1s2). Recently, Li and Rosmej34 proposed an analytical b-potential approach based on the MCDF-SCFTIS model, in which one adjustable parameter b was introduced to characterize the plasma-electron density. In order to get the results agreed with the experimental results, b = 4 and b = 2 are applied to the calculations for Al11+ (1s2p−1s2) and Cl15+ (1s3p−1s2), respectively. Whereas, as discussed below, the present model does not need any adjustable parameter although the plasma screening effects are dependent on the specific bound state considered.
From the atomic-physic view of point, there are three kinds of interaction/correlation in plasma: the one between free electrons, the one between free electron and ion (bound electron), and the one between ion and ion. In order to consider the correlations between free electron and ion, the present model include the contribution of negative-energy electron through considering the three-body recombination process between target ion and plasma electrons. As shown in Eq. (6), the negative-energy electron density is state-dependent on the target ions studied since that a condition of \(\varepsilon _{\mathrm{p}} \,> \,\varepsilon _{\mathrm{b}}\) is used to guarantee the quantum degeneracy between the initial and recombined bound electrons, where \(\varepsilon _{\mathrm{p}}\) is the energy of recombined electron and \(\varepsilon _{\mathrm{b}}\) is the initial outermost orbital energy. In the calculations of the line shifts, \(\varepsilon _{\mathrm{p}} \;> \; \varepsilon _{3p}\) and \(\varepsilon _{\mathrm{p}} \,> \,\varepsilon _{2p}\) are applied for Cl15+ (1s3p−1s2) and Al11+ (1s2p−1s2), respectively. In order to gain insight into the dependence of plasma-electron density on \(\varepsilon _{\mathrm{b}}\), the electron density fluctuations \(\delta \rho \left( r \right)\) of Al11+ ion are computed and shown in Fig. 3b for different energies (\(\varepsilon _{2p}\) and \(\varepsilon _{3p}\)). It is found that the \(\delta \rho \left( r \right)\) of \(\varepsilon _{2p}\) is significantly larger than the one of \(\varepsilon _{3p}\). This indicates that the plasma-electron density distribution is sensitive to the specific bound state studied, which has also been verified by the good agreements with line-shift experiments27,28.
Validation
The calculated electron density distributions of the target ions depend on the models used. For further validation of the present model, we performed CMD simulations to the electron density distribution around the target ion of UNPs because it is a good prototype to study the many-body effects of moderately coupled plasmas using the CMD method. As pointed by Bergeson et al. in their review paper42, UNPs display the physics of strongly coupled and moderately shielded plasmas without quantum degeneracy. The details of the CMD simulations are provided in Supplementary Note 2. The obtained CMD results of electron density fluctuation \(\delta \rho \left( r \right)\) are presented in Fig. 5 together with those of Fermi–Dirac distribution and Debye–Hückel model for (a) \(\,\rho _{\mathrm{e}} = 10^9{\mathrm{cm}}^{ - 3},\,T_{\mathrm{e}} = 5.5{\mathrm{K}},\Gamma _{\mathrm{e}} = 0.49\) and (b) \(\rho _{\mathrm{e}} = 10^9\,{\mathrm{cm}}^{ - 3},\,T_{\mathrm{e}} = 11.5{\mathrm{K}},\Gamma _{\mathrm{e}} = 0.23\). It is shown that the results of the present model are in very good agreement with those of CMD simulations, while the results of the other two models apparently deviate from those of CMD simulations. The model of the Fermi–Dirac distribution obviously overestimates the plasma-electron densities near the target ion, indicating the non-equilibrium feature of the electron distributions. In Debye–Hückel model, the electron density distribution \(\rho \left( r \right) = \rho _0[1 + e{{\Phi }}(r)/(k_{\mathrm{B}}T)]\) used is a linear approximation of the Boltzmann distribution \(\rho \left( r \right) = \rho _0{\mathrm{exp}}[ - e{{\Phi }}(r)/(k_{\mathrm{B}}T)]\), which causes obvious underestimation of the electron density near the target ion, as shown in Fig. 5.
In order to further explore the effect of recombined bound electron distribution, the free-electron density distributions from the present model are compared to those from the CMD simulations. The good agreements are shown again in between the CMD and the present model. Note that free-electron density of the present model is the same as the one of Fermi–Dirac distribution. This indicates that the difference between the full Fermi–Dirac distribution and CMD simulation comes from the different treatments of the negative-energy electron distributions. According to our personal communication with Jie Yang and Feng Fang, the important contributions of the three-body recombination processes on the electron distribution of the target ion are observed lately in the UNPs experiment, in which a large amount of highly excited Rydberg state Rb atoms are found be produced from the three-body recombination processes between Rb+ ion and two free electrons of the surrounding plasma. It is tempted to conclude that Boltzmann or Fermi–Dirac distribution theory would be inapplicable to dense or moderately/strongly coupled plasmas where three-body recombination processes become important.
Note that only the static plasma screening effects are included in the present work. When modeling screaming plasmas or investigating the atomic processes with the non-negligible motion of ions in plasma43,44,45, the effects of dynamic screening should be further considered. For example, in the investigation of dynamic plasma screening effects on ion–ion collisions45, the static Debye–Hückel model is found to overestimate the plasma-screening effects on the electron capture process, and the dynamic screening effects can be reduced to the static plasmas screening effects when the velocity of projectile ion is smaller than the electron thermal velocity. The present model will be extended to consider the dynamic screening effect of dense plasmas in combination with the quantum statistical approach31 in our future work.
Conclusion
In summary, a universal electron screening model is proposed for treating the electron screening effects of dense or moderately/strongly coupled plasmas, in which the three-body recombination processes are found to be important in determining the electron density distribution around target ions in plasmas. Due to the quantum degeneracy effect between the recombined and initially bound electrons, the electron distribution of the target ion is sensitive to the specific bound state studied, which further influences the ion energy levels and line shifts. The proposed atomic-state-dependent model opens a promising way to treat the electron screening effect on atoms embedded in warm/hot dense plasma, which is essential for the investigation of atomic structure and dynamics in plasmas, as well as the spectra and EOS of plasma. Apart from the three-body recombination processes, this work constructs a theoretical framework to couple other inelastic collision and radiative processes to the screening effect, which will be considered in our future work. Next, we will further apply the present model to treat the plasmas with a wide range of temperatures and densities. We may devote machine learning technique46 to construct a more convenient analytic potential. This work is expected to provide an effective approach to handle those challenging questions existing in related studies of high-energy-density physics, such as astrophysical objects (stars, planets), inertial confinement fusion, and the matter properties in extreme conditions.
Methods
Numerical calculations
In the present screening model, total effective potential \({{\Phi }}({\boldsymbol{r}})\) and plasma-electron density fluctuation \(\delta \rho \left( {\boldsymbol{r}} \right)\) are numerically calculated by employing Eqs. (6) and (7). For a system with a given mean free-electron density \(\rho _{\mathrm{e}}\) and electron temperature Te, the chemical potential μ in Eq. (1) meets with
and can be calculated by the accurate Padé approximants to the Fermi–Dirac integrals and their inversions47. Then \({{\Phi }}({\boldsymbol{r}})\) and \(\delta \rho \left( {\boldsymbol{r}} \right)\) are only dependent to each other and can be calculated with an iteration approach. Note that \({\mathbf{\Phi }}({\it{r}})\) and \(\delta \rho \left( {\it{r}} \right)\) decrease to zero exponentially at large r, which is similar with the one of Debye–Hückel model. The total effective potential energy \(V\left( {\boldsymbol{r}} \right)\) can be obtained as \(V\left( {\boldsymbol{r}} \right) = - e{{\Phi }}\left( {\boldsymbol{r}} \right)\) by using Eq. (7), in which the third term of \(\delta V\left( {\boldsymbol{r}} \right) = {\int} {\frac{{e^2}}{{4\pi \varepsilon _0\left| {{\boldsymbol{r}} - {\boldsymbol{r}}\prime } \right|}}\delta \rho ({\boldsymbol{r}}^\prime ){\mathrm{d}}{\boldsymbol{r}}^\prime }\) represents the perturbation one due to the presence of target ion.
Level-shift calculations
Once the plasma-electron density fluctuation is determined, the perturbation potential energy \(\delta V\left( {\boldsymbol{r}} \right)\) can be obtained. When the screening effects on an atom in state j are not very strong, the atomic energy level shift due to the presence of surrounding plasma can be calculated using the first-order perturbation theory
Here, \(P_j\left( r \right)\) and \(Q_j\left( r \right)\) are the relativistic radial wave functions of the large and small components, respectively. Compared with other models, the present model includes the contributions of three-body recombination processes and thus it is expected to be more accurate in the treatment of moderately/strongly coupled or dense plasmas.
In short, the atomic level shift in plasma can be computed with the present model with following steps: (I) the wave functions \(P_j\left( r \right)\) and \(Q_j\left( r \right)\) of the target ion are calculated using the multi-configuration Dirac–Fock approach; (II) the total effective potential \({{\Phi }}({\boldsymbol{r}})\) and the plasma-electron density fluctuation \(\delta \rho \left( {\boldsymbol{r}} \right)\) can be calculated using Eqs. (6) and (7) with an iteration method; (III) the atomic energy level shift can be obtained with Eq. (9) based on the first-order perturbation theory.
Data availability
The data that support the plots within this paper are available from the corresponding author upon reasonable request.
Code availability
The code that supports the theoretical plots within this paper is available from the corresponding author upon reasonable request.
References
Tayler, R. J. The Stars: their Structure and Evolution (Cambridge University Press, 1994).
Helled, R., Anderson, J. D., Podolak, M. & Schubert, G. Interior models of uranus and Neptune. Astrophys. J. 726, 15 (2011).
Lindl, J. D. et al. The physics basis for ignition using indirect-drive targets on the national ignition facility. Phys. Plasmas 11, 339 (2004).
Hu, S. X., Militzer, B., Goncharov, V. N. & Skupsky, S. Strong coupling and degeneracy effects in inertial confinement fusion implosions. Phys. Rev. Lett. 104, 235003 (2010).
Vinko, S. M. et al. Creation and diagnosis of a solid-density plasma with an x-ray free-electron laser. Nature 482, 59 (2012).
Ciricosta, O. et al. Direct measurements of the ionization potential depression in a dense plasma. Phys. Rev. Lett. 109, 065002 (2012).
Ciricosta, O. et al. Measurements of continuum lowering in solid-density plasmas created from elements and compound. Nat. Commun. 7, 11713 (2016).
Hurricane, O. A. et al. Fuel gain exceeding unity in an inertially confined fusion implosion. Nature 506, 343 (2014).
Gomez, M. R. et al. Experimental demonstration of fusion-relevant conditions in magnetized liner inertial fusion. Phys. Rev. Lett. 113, 155003 (2015).
Bailey, J. E. et al. A higher-than predicted measurement of iron opacity at solar interior temperatures. Nature 517, 56 (2015).
Nagayama, T. et al. Systematic study of L-shell opacity at stellar interior temperatures. Phys. Rev. Lett. 122, 235001 (2019).
Janev, R. K., Zhang, S. & Wang, J. Review of quantum collision dynamics in Debye plasmas. Matter Radiat. Extremes 1, 237 (2016).
Ma, Y. et al. KLL dielectronic recombination of hydrogenlike carbon ion in Debye plasmas. J. Quant. Spectrosc. Radiat. Transf. 241, 106731 (2020).
Salzmann, D. Atomic Physics in Hot Plasmas (Oxford University Press, New York, 1998).
Griem, H. R. Principles of Plasma Spectroscopy (Cambridge University Press, Cambridge, 1997).
Debye, P. & Hückel, E. The interionic attraction theory of deviations from ideal behavior in solution. Phys. Z. 24, 185 (1923).
Ichimaru, S. Strongly coupled plasmas: high-density classical plasmas and degenerate electron liquids. Rev. Mod. Phys. 54, 1017 (1982).
Zérah, G., Clérouin, J. & Pollock, E. L. Thomas–Fermi molecular-dynamics, linear screening, and mean-field theories of plasmas. Phys. Rev. Lett. 69, 446 (1992).
Crowley, B. J. B. Average-atom quantum-statistical cell model for hot plasma in local thermodynamic equilibrium over a wide range of densities. Phys. Rev. A 41, 2179 (1990).
Ecker, G. & Kröll, W. Lowering of the ionization energy for a plasma in thermodynamic equilibrium. Phys. Fluid 6, 62 (1963).
Stewart, J. C. & Pyatt, K. D. Jr Lowering of ionization potentials in plasmas. Astrophys. J. 144, 1203 (1966).
Rosmej, F., Bennadji, K. & Lisitsa, V. S. Effect of dense plasmas on exchange-energy shifts in highly charged ions: an alternative approach for arbitrary perturbation potentials. Phys. Rev. A 84, 032512 (2011).
Li, X. & Rosmej, F. B. Quantum-number-dependent energy level shifts of ions in dense plasmas: a generalized analytical approach. Eur. Phys. Lett. 99, 33001 (2012).
Li, X., Rosmej, F. B., Lisitsa, V. S. & Astapenko, V. A. An analytical plasma screening potential based on the self-consistent-field ion-sphere model. Phys. Plasmas 26, 033301 (2019).
Hoarty, D. J. et al. Observations of the effect of ionization-potential depression in hot dense plasma. Phys. Rev. Lett. 110, 265003 (2013).
Fletcher, L. B. et al. Observations of continuum depression in warm dense matter with x-ray thomson scattering. Phys. Rev. Lett. 112, 145004 (2014).
Stillman, C. R. et al. Picosecond time-resolved measurements of dense plasma line shifts. Phys. Rev. E 95, 063204 (2017).
Beiersdorfer, P. et al. High-resolution measurements of Cl 15+ line shifts in hot, solid-density plasmas. Phys. Rev. A 100, 012511 (2019).
Son, S. K., Thiele, R., Jurek, Z., Ziaja, B. & Santra, R. Quantum-mechanical calculation of ionization-potential lowering in dense plasmas. Phys. Rev. X 4, 031004 (2014).
Lin, C., Röpke, G., Kraeft, W. D. & Reinholz, H. Ionization-potential depression and dynamical structure factor in dense plasmas. Phys. Rev. E 96, 013202 (2017).
Lin, C. Quantum statistical approach for ionization potential depression in multi-component dense plasmas. Phys. Plasmas 26, 122707 (2019).
Vinko, S. M., Ciricosta, O. & Wark, J. S. Density functional theory calculations of continuum lowering in strongly coupled plasmas. Nat. Commun. 5, 3533 (2014).
Calisti, A., Ferri, S. & Talin, B. Ionization potential depression for non-equilibrated aluminum plasmas. J. Phys. B 48, 224003 (2015).
Li, X. & Rosmej, F. B. Analytical approach to level delocalization and line shifts in finite temperature dense plasmas. Phys. Lett. A 384, 126478 (2020).
Chen, Z. B. Calculation of the energies and oscillator strengths of Cl15+ in hot dense plasmas. J. Quant. Spectrosc. Radiat. Transf. 237, 106615 (2019).
Chen, Z. B. & Wang, K. Theoretical study on the line shifts of He-like Al11+ ion immersed in a dense plasma. Radiat. Phys. Chem. 172, 108816 (2020).
Gu, M. F. & Beiersdorfer, P. Stark shift and width of x-ray lines from highly charged ions in dense plasmas. Phys. Rev. A 101, 032501 (2020).
Iglesias, C. A. On spectral line shifts from analytic fits to the ion-sphere model potential. High Energy Density Phys. 30, 41–44 (2019).
Singh, A. K. et al. Plasma screening effects on the atomic structure of He-like ions embedded in strongly coupled plasma. Phys. Lett. A 384, 126369 (2020).
Jönsson, P., He, X., Fischer, C. F. & Grant, I. P. The grasp2K relativistic atomic structure package. Comput. Phys. Commun. 177, 597–622 (2007).
Jönsson, P., He, X., Fischer, C. F. & Grant, I. P. (2007). The grasp2K relativistic atomic structure package. Comput. Phys. Commun. 184, 2197–2203 (2013).
Bergeson, S. D. et al. Exploring the crossover between high-energy-density plasma and ultracold neutral plasma physics. Phys. Plasmas 26, 100501 (2019).
Moldabekov, Z., Dornheim, T. & Bonitz, M. Screening of a test charge in a free-electron gas at warm dense matter and dense non-ideal plasma conditions. Contrib. Plasma Phys. 61, e202000176 (2021).
Dornheim, T. et al. Effective static approximation: a fast and reliable tool for warm-dense matter theory. Phys. Rev. Lett. 125, 235001 (2020).
Jung, Y. D. Dynamic plasma screening effects on electron capture process in hydrogenic ion-fully stripped ion collisions in dense plasmas. Phys. Plasmas 4, 2756 (1997).
Zhang, L., Han, J., Wang, H., Car, R. & Weinan, E. Deep potential molecular dynamics: a scalable model with the accuracy of quantum mechanics. Phys. Rev. Lett. 120, 143001 (2018).
Antia, H. M. Rational function approximations for Fermi–Dirac integrals. Astrophys. J. Suppl. Ser. 84, 101 (1993).
Acknowledgements
This work was supported by the National Key Research and Development Program of China under Grants Nos. 2017YFA0402300 and 2017YFA0403200 and the National Natural Science Foundation of China (Grants Nos. 11934004, 11704040, 11534011, and U1530261).
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F.Z., Y.W., Y.Q., and J.W. designed the research and wrote the manuscript. Theoretical tasks were carried out by F.Z. under the supervision of Y.W., Y.Q., and J.W. Numerical simulations were carried out by F.Z., J.G., and Y.M.
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Zhou, F., Qu, Y., Gao, J. et al. Atomic-state-dependent screening model for hot and warm dense plasmas. Commun Phys 4, 148 (2021). https://doi.org/10.1038/s42005-021-00652-x
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DOI: https://doi.org/10.1038/s42005-021-00652-x
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